Polyurethane sponges bearing cucurbituril adsorb Cr(III) and Pb(II) ions from contaminated water samples.

Water contamination with toxic metals causes harmful effects on the environment and to human health. Although cucurbiturils have carboxyl groups in their portal that can interact with metal ions, there is a lack of studies about their use as metal adsorbent. This scenario has motivated conduction of the present study, which addresses the use of cucurbit[6]uril (CB[6]) and cucurbit[8]uril (CB[8]) for adsorbing Pb and Cr from water samples, in free forms and immobilized in poly(urethane) sponges. The adsorption kinetics revealed that CB[8] leads to faster adsorption compared to CB[6], with equilibrium achieved in 8 h for CB[8] and 48 h for CB[6] for both metals, and achieved up to 80% of decrease in metal concentration. The Langmuir isotherm model provided a better description of adsorption for Cr and Pb in CB[6] and Pb in CB[8] with a maximum concentration adsorbed of 32.47 mg g-1 for Pb in CB[6], while the Dubinin-Radushkevich model was more suitable for Cr adsorption in CB[8]. Sponges containing CB[6] and CB[8] have proven to be efficient for Pb and Cr remediation in tannery effluent samples, reducing Cr and Pb concentration by 42 and 33%, respectively. The results indicate that CB[6] and CB[8], whether used in their pure form or integrated into sponges, exhibit promising potential for efficiently adsorbing metals in aqueous contaminated environments.

From classic methodologies to application of nanomaterials for soil remediation: an integrated view of methods for decontamination of toxic metal(oid)s.

Soil pollution with toxic elements is a recurrent issue due to environmental disasters, fossil fuel burning, urbanization, and industrialization, which have contributed to soil contamination over the years. Therefore, the remediation of toxic metals in soil is always an important topic since contaminated soil can affect the environment, agricultural safety, and human health. Many remediation methods have been developed; however, it is essential to ensure that they are safe, and also take into account the limitation of each methodology (including high energy input and generation of residues). This scenario has motivated this review, where we explore soil contamination with arsenic, lead, mercury, and chromium and summarize information about the methods employed to remediate each of these toxic elements such as phytoremediation, soil washing, electrokinetic remediation, and nanoparticles besides elucidating some mechanisms involved in the remediation. Considering all the discussed techniques, nowadays, different techniques can be combined together in order to improve the efficiency of remediation besides the new approach of the techniques and the use of one technique for remediating more than one contaminant.

Iron oxide nanoparticle phytotoxicity to the aquatic plant Lemna minor: effect on reactive oxygen species (ROS) production and chlorophyll a/chlorophyll b ratio.

Although iron oxide occurs naturally in the environment, iron oxide nanoparticles have distinct mobility, reactivity, and toxicity, which can harm the human health and nature. This scenario has motivated the investigation of the toxic effects of iron oxide nanoparticles (akaganeite predominance + hematite) on the aquatic plant Lemna minor. First, nanoparticles were synthesized and characterized; then, different iron oxide NP concentrations were added to Lemna minor culture. After 7 days, all the Lemna minor leaves died, irrespective of the added NP concentration. The iron oxide NP impact on the plant was evaluated based on malondialdehyde (MDA) production from thiobarbituric acid reactive substances (TBARS), which was dose-dependent; i.e., lipid peroxidation in the plant increased with rising iron oxide NP concentration. The chlorophyll content decreased at high iron oxide NP concentrations, which disrupted the light absorption mechanism. Fe accumulation in Lemna minor roots also occurred, which can harm nutrient uptake. Therefore, the iron oxide NP toxic impact on plants and related ecosystems requires further studies in order to prevent environmental damage.

CaI and SrI molecules for iodine determination by high-resolution continuum source graphite furnace molecular absorption spectrometry: Greener molecules for practical application.

A new method to determine iodine in drug samples by high-resolution continuum source graphite furnace molecular absorption spectrometry (HR-CS GF MAS) has been developed. The method measures the molecular absorption of a diatomic molecule, CaI or SrI (less toxic molecule-forming reagents), at 638.904 or 677.692nm, respectively, and uses a mixture containing 5µg of Pd and 0.5µg of Mg as chemical modifier. The method employs pyrolysis temperatures of 1000 and 800°C and vaporization temperatures of 2300 and 2400°C for CaI and SrI, respectively. The optimized amounts of Ca and Sr as molecule-forming reagents are 100 and 150µg, respectively. On the basis of interference studies, even small chlorine concentrations reduce CaI and SrI absorbance significantly. The developed method was used to analyze different commercial drug samples, namely thyroid hormone pills with three different iodine amounts (15.88, 31.77, and 47.66µg) and one liquid drug with 1% m v-1 active iodine in their compositions. The results agreed with the values informed by the manufacturers (95% confidence level) regardless of whether CaI or SrI was determined. Therefore, the developed method is useful for iodine determination on the basis of CaI or SrI molecular absorption.

Lead concentrations in whole blood, serum, saliva and house dust in samples collected at two time points (12 months apart) in Santo Amaro, BA, Brazil.

UNLABELLED: Whole Blood Lead Level (BLL) is the main marker used to verify lead contamination. The present study explores how BLL is associated with lead concentrations in serum, saliva and house dust. Samples were collected twice from Santo Amaro, BA, Brazil, a region that was contaminated by a lead smelter in the past; a time interval of 12 months was allowed between the two collections. It is noteworthy that the following measures have recently been taken to diminish exposure of the population to lead: streets have been paved with asphalt, and educational campaigns have been launched to reduce exposure to contaminated dust. RESULTS: Compared with the first time point, all the samples collected at the second time point contained lower lead concentration (p<0.05), which suggested that the adopted measures effectively reduced exposure of the population to lead present in contaminated soil and dust. Statistically significant correlations only existed between lead in blood collected in the first year and lead in blood collected in the second year (Spearman's r=0.55; p<0.0001; n=62), and lead in house dust collected in the first year and lead in house dust collected in the second year (Spearman's r=0.5; p<0.0001; n=59). CONCLUSIONS: Results support the validity of lead determination in blood and in house dust to assess lead exposure over time. However, lead in blood and lead in dust did not correlate with lead in serum or lead in saliva.

Reduced bone and body mass in young male rats exposed to lead.

The aim of this study was to see whether there would be differences in whole blood versus tibia lead concentrations over time in growing rats prenatally. Lead was given in the drinking water at 30 mg/L from the time the dams were pregnant until offspring was 28- or 60-day-old. Concentrations of lead were measured in whole blood and in tibia after 28 (28D) and 60 days (60D) in control (C) and in lead-exposed animals (Pb). Lead measurements were made by GF-AAS. There was no significant difference (P > 0.05) in the concentration of whole blood lead between Pb-28D (8.0 ± 1.1 µg/dL) and Pb-60D (7.2 ± 0.89 µg/dL), while both significantly varied (P < 0.01) from controls (0.2 µg/dL). Bone lead concentrations significantly varied between the Pb-28D (8.02 ± 1.12 µg/g) and the Pb-60D (43.3 ± 13.26 µg/g) lead-exposed groups (P < 0.01), while those exposed groups were also significantly higher (P < 0.0001) than the 28D and 60D control groups (Pb < 1 µg/g). The Pb-60D group showed a 25% decrease in tibia mass as compared to the respective control. The five times higher amount of lead found in the bone of older animals (Pb-60D versus Pb-28D), which reinforces the importance of using bone lead as an exposure biomarker.

Determination of cadmium in biological samples solubilized with tetramethylammonium hydroxide by electrothermal atomic absorption spectrometry, using ruthenium as permanent modifier.

The feasibility of Ru as a permanent modifier for the determination of Cd in biological samples treated with tetramethylammonium hydroxide (TMAH) by ET AAS was investigated. The tube treatment with Ru was carried out only once and lasted for about 300 atomization cycles. The pyrolysis and atomization temperatures, 750 degrees C and 1300 degrees C, respectively, were chosen from the temperature curves. The sample dissolution procedure was very simple: a sample aliquot was mixed with a small volume of a 25% m/v TMAH solution, the volume was made up to 50 ml and the mixture was kept at 60 degrees C for 1 h. Six certified biological reference materials were analyzed and the obtained Cd concentrations are within the 95% confidence interval of the certified values, proving the accuracy of the proposed procedure for a variety of biological samples. The calibration curve, with correlation coefficient higher than 0.99, was established for a working range up to 10 microg l(-1). The precision was good as demonstrated by relative standard deviations below 3%, except for one sample. The limit of detection (3sigma) was 0.05 microg l(-1) and the characteristic mass was 1.30 pg, obtained in the presence of the Ru modifier.